Indirect Dynamics in a Highly Exoergic Substitution Reaction
نویسندگان
چکیده
منابع مشابه
Indirect dynamics in a highly exoergic substitution reaction.
The highly exoergic nucleophilic substitution reaction F(-) + CH3I shows reaction dynamics strikingly different from that of substitution reactions of larger halogen anions. Over a wide range of collision energies, a large fraction of indirect scattering via a long-lived hydrogen-bonded complex is found both in crossed-beam imaging experiments and in direct chemical dynamics simulations. Our me...
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generate recursively the infinite Prouhet-Thue-Morse word 0110100110010110 and Fibonacci word 01001010010010100101, respectively [1]. What can be said about the entropy (loosely, the amount of disorder) if we introduce some randomness into such definitions? If [2, 3] ⎨⎩ 0→ 1⁄2 01 with probability 12 10 with probability 12 1→ 0 with independence assumed throughout, then the set of possi...
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ژورنال
عنوان ژورنال: Journal of the American Chemical Society
سال: 2013
ISSN: 0002-7863,1520-5126
DOI: 10.1021/ja308042v